Evidence map›Paper›PMID 41261935›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Intertwined Processes in the Pummerer-Type Rearrangement Affording α-Trifluoromethoxylated Thioethers and the Corresponding Highly Enantioenriched Sulfoxides.

Nicolas Moget, Jérémy Saiter, Fabien Toulgoat, Thierry Billard, Frédéric Leroux, Armen Panossian, Gilles Hanquet

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Nicolas MogetUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042 - LIMA, ECPM, 25, rue Becquerel, Strasbourg, 67087, France.
Jérémy SaiterUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042 - LIMA, ECPM, 25, rue Becquerel, Strasbourg, 67087, France.
Fabien ToulgoatCPE Lyon, Campus LyonTech-La Doua, 43 Bd du 11 novembre 1918, Villeurbanne, 69616, France.
Thierry BillardInstitute of Chemistry and Biochemistry (ICBMS-UMR CNRS5246), CNRS, Université Lyon1, CPE Lyon, 43 Bd du 11Novembre 1918, Lyon, 69622, France.
Frédéric LerouxUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042 - LIMA, ECPM, 25, rue Becquerel, Strasbourg, 67087, France.ORCID https://orcid.org/0000-0001-8900-5753
Armen PanossianUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042 - LIMA, ECPM, 25, rue Becquerel, Strasbourg, 67087, France.ORCID https://orcid.org/0000-0003-2317-1200
Gilles HanquetUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042 - LIMA, ECPM, 25, rue Becquerel, Strasbourg, 67087, France.ORCID https://orcid.org/0000-0001-8829-1225

Funding

Agence Nationale de la Recherche ANR-20-CE07-0004-02 (Ap-PET-I)Fondation Jean-Marie Lehn (formerly Centre International de Recherche aux Frontières de la Chimie) FLR-FRC-004(DiFluChir)
6 · The paper itself

Abstract

A method to access racemic or highly stereoenriched α-trifluoromethoxylated sulfoxides through the Pummerer rearrangement of aryl methyl sulfoxides followed by the oxidation of the resulting trifluoromethoxylated sulfides is described. Among the three reagents selected as both rearrangement activators and F

Indexed as

C‐sp3–OCF3 stereocenterfluorophosgenesulfoxidationsulfoxidetrifluoromethoxylation

Identifiers

PMID41261935
PMCPMC12731534

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.