ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Boron Nitride Reinforced Supramolecular Gels Nano-Assembled with Fungicides toward Soil-Borne Fungal Disease Management.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Boron Nitride Reinforced Supramolecular Gels Nano-Assembled with Fungicides toward Soil-Borne Fungal Disease Management.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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Authors and funding
10 authors.
Funding
Abstract
To overcome limitations of conventional fungicides against soil-borne diseases like southern blight, this study develops h-BN-reinforced supramolecular gels for precision tebuconazole (Teb) delivery. These gels are engineered organic solvent free via one-step amino-amide self-assembly with polyprotic acids. h-BN nanosheets embed uniformly within the gel matrices with narrowing pore distributions and enhancing mechanical stability. h-BN's hydrophobicity, affinity for the gel's carbon chains, and π-π interactions with Teb collectively restricts Teb diffusion, reducing its cumulative release rate. The gels' inherent pH and temperature-responsive gel-sol transitions enable dual stimuli-responsive sustained fungicide release. The h-BN reinforced carriers exhibit superior interfacial properties, reducing contact angles due to h-BN's hydrophobicity and capillary channel formation. Fluorescence after rinsing confirms significantly boosted adhesion and rain resistance versus commercial formulations. Interactions with soil are tunable by h-BN disrupted the supramolecular structure, exposing Teb for moderate soil adsorption while extending Teb retention time (940 min, 14.69 times longer than free Teb) and enhancing root-zone retention (41.45% vs. 13.48% for commercial). Such system also shows superior efficacy against Sclerotium rolfsii (EC
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