ArticleNature communications2025
Inverse design of structural colours in polymeric films with crystallization-induced reversible thermochromism.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Precisely controlling structural colours in polymeric materials remains a major challenge, with current approaches often relying on trial-and-error synthesis. Here, we develop a colour design model, enabling inverse design of structural colours in bottlebrush block copolymers (BBCPs). The model can quantitatively link BBCP molecular structures to macroscopic colours through the integration of a strong segregation self-consistent field theory model with a multilayer optical framework. We first validate its predictive capability by synthesising and assembling BBCPs with varied chain architectures to produce a full colour spectrum, and then demonstrate its generalisability to other BBCP chemistries. In addition, we observe reversible, nonlinear thermochromism in systems combining a crystalisable block with a soft, low-glass transition temperature segment, while similar BBCPs lacking this pairing show no such response. Our work establishes a predictive platform for designing structurally coloured, thermoresponsive polymeric materials and advances the rational engineering of photonic soft matter.
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