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ArticleChemSusChem2025

Life Cycle Assessment of Solvothermal Zeolitic Imidazolate Framework-8 Synthesis: Is the Substitution of N,N-Dimethylformamide with Glycerol Carbonate Environmentally Sustainable?

Alessandra Sessa, Eleonora Rossi, Prisco Prete, Fabrizio Passarini, Masaki Itatani, Federico Rossi, Istvan Lagzi, Pierandrea Lo Nostro, Daniele Cespi, Raffaele Cucciniello

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Article in ChemSusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Alessandra SessaDepartment of Chemistry and Biology "Adolfo Zambelli", Salerno University, Fisciano, Italy.
Eleonora RossiDepartment of Industrial Chemistry "Toso Montanari", Alma Mater Studiorum - University of Bologna, Bologna, Italy.
Prisco PreteDepartment of Chemistry and Biology "Adolfo Zambelli", Salerno University, Fisciano, Italy.
Fabrizio PassariniDepartment of Industrial Chemistry "Toso Montanari", Alma Mater Studiorum - University of Bologna, Bologna, Italy.
Masaki ItataniDepartment of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Japan.
Federico RossiDepartment of Physical Sciences, Earth and Environment, University of Siena, Siena, Italy.
Istvan LagziDepartment of Physics, Institute of Physics, Budapest University of Technology and Economics, Budapest, Hungary.
Pierandrea Lo NostroDepartment of Chemistry "Ugo Schiff", University of Florence, Firenze, Italy.
Daniele CespiDepartment of Industrial Chemistry "Toso Montanari", Alma Mater Studiorum - University of Bologna, Bologna, Italy.ORCID https://orcid.org/0000-0002-6348-6111
Raffaele CuccinielloDepartment of Chemistry and Biology "Adolfo Zambelli", Salerno University, Fisciano, Italy.ORCID https://orcid.org/0000-0002-3291-7273

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In this work, a comparative life cycle assessment of the solvothermal synthesis of zeolitic imidazolate framework (ZIF-8) is reported. ZIF-8 is listed among the most representative structures of ZIFs, an emerging subclass of metal-organic frameworks (MOFs). ZIF-8 is commonly synthesized through the solvothermal method, and the election solvents are currently N, N-dimethylformamide (DMF) and water, both allowing the production of highly crystalline ZIF-8 with a high specific surface area. Considering the recently introduced severe restrictions on the use of DMF as defined very recently by European Chemical Agency, an innovative synthetic procedure in the biobased and nontoxic glycerol carbonate (GlyC) was reported. This approach delivers mesoporous ZIF-8 with high crystallinity and high specific surface area. The present study suggests a cradle-to-gate life cycle assessment of the laboratory scale ZIF-8 synthesis, comparing the same process in DMF and GlyC in terms of their environmental impacts. The results help to demonstrate that the respect of the 7

Indexed as

biobasedglycerol carbonatelife cycle assessment (LCA)solvothermalzeolitic imidazolate framework (ZIF‐8)

Identifiers

PMID41243892
PMCPMC12703451

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.