Evidence map›Paper›PMID 41234189›Full record

ArticleJournal of the American Chemical Society2025

Competitive Adsorption and Modulated Product Binding Using Pyridines on Cobalt Phosphide Enhance Hydrogenation Catalysis.

Nina A Arnosti, Gregor P Wasser, Yu-Chun Shen, Murielle F Delley

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Nina A ArnostiDepartment of Chemistry, University of Basel, Basel 4058, Switzerland.
Gregor P WasserDepartment of Chemistry, University of Basel, Basel 4058, Switzerland.ORCID 0009-0009-5174-2147
Yu-Chun ShenDepartment of Chemistry, University of Basel, Basel 4058, Switzerland.ORCID 0009-0004-0987-2742
Murielle F DelleyDepartment of Chemistry, University of Basel, Basel 4058, Switzerland.ORCID 0000-0001-6450-5540

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The binding and interaction of substrates, products, and other reaction components at the surface are key to heterogeneous catalysis. Improved catalytic properties can be obtained from organic ligands that interact with the substrate at the surface. However, competitive binding phenomena of the ligands with not only substrates but also intermediates and products of a reaction can critically influence catalysis. The tuning of these interfacial phenomena to achieve a selective hydrogenation of α,β-unsaturated aldehydes is underexplored with heterogeneous catalysts, in particular, with transition metal phosphide-based catalysts. Herein, we systematically investigated the effect of seven pyridine-based additives with varied electronic, steric, and structural properties on the hydrogenation of

Identifiers

PMID41234189
PMCPMC12673588

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.