ArticlePolymers2025
Feasibility Study on Quantification of Biodegradable Polyester Microplastics Based on Intrinsic Fluorescence.
Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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12 authors.
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Abstract
While biodegradable plastics alleviate plastic pollution, their degradation-derived biodegradable microplastics (BMPs) pose new ecological risks, necessitating efficient quantification methods. This study explores a label-free approach by leveraging the intrinsic fluorescence of common biodegradable polyesters (PLA, PHB, PBS, PBAT, PCL). We find that biodegradable microplastics exhibit two types of characteristic fluorescence emission: one originating from molecular functional groups and the other originating from the chromophore formed by the aggregation of conjugated groups. Using PBAT as a model, we confirm that fluorescence intensity depends on the BMPs' size and shape. Under 380 nm excitation, concentration-dependent signals are observed at 436 nm (indirectly from PBAT-enhanced water Raman scattering) and 465 nm (directly from PBAT intrinsic fluorescence), leading to successful linear models between BMPs' mass concentration and fluorescence intensity over 100-500 mg/L, with correlation coefficients (R
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