Evidence map›Paper›PMID 41228636›Full record

ArticlePolymers2025

The Influence of Zinc Stearate Complexes on the Sulfur Vulcanization of Ethylene-Propylene-Diene Monomer.

Krzysztof Kaczewiak, Piotr Głąb, Magdalena Maciejewska

Abstract read
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Krzysztof KaczewiakInterdisciplinary Doctoral School, Lodz University of Technology, 116 Żeromskiego Street, 90543 Lodz, Poland.ORCID 0000-0002-5376-0252
Piotr GłąbHutchinson Poland Sp z o.o., 130 Kurczaki Street, 90543 Lodz, Poland.ORCID 0009-0002-4728-6555
Magdalena MaciejewskaInstitute of Polymer and Dye Technology, Lodz University of Technology, 16 Stefanowskiego Street, 90543 Lodz, Poland.ORCID 0000-0001-7110-290X

Funding

Ministry of Science and Higher Education DWD/6/0559/2022
6 · The paper itself

Abstract

This article explores the influence of synthesized zinc stearate (ZnSt) complexes with different molar ratios of zinc oxide (ZnO) and stearic acid (StA) on the sulfur vulcanization and properties of the ethylene-propylene-diene monomer (EPDM). The aim of study was to reduce the amount of ZnO in elastomer composites without affecting their compression set. The research involves synthesizing zinc complexes, including the addition of sulfur, and using them as activators in EPDM compounds. The synthesized products were characterized using DSC and FTIR to identify their composition and thermal properties. The results of the compression set and equilibrium swelling tests indicated that ZnO was used in excess as an activator. Zinc complexes allowed for a significant reduction in zinc content compared to ZnO. The stoichiometric salt of ZnO and StA was the most effective in terms of vulcanization parameters and the compression set. Non-stoichiometric complexes were less effective, proportionally to their content. SEM images showed that the dispersion of components was relatively homogeneous in vulcanizates with active ZnO and commercial ZnSt. However, the blooming of ZnSt from vulcanizates was observed. Thus, using synthesized materials could reduce the zinc content in EPDM composites while maintaining good properties, but a further reduction is needed to avoid blooming.

Indexed as

carbon footprintcompression setcross-linking densityelastomersEPDM

Identifiers

PMID41228636
PMCPMC12611030

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.