ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Heavy Prussian Blue Analog with Magnetic Ordering above 400 K.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Heavy Prussian Blue Analog with Magnetic Ordering above 400 K.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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9 authors.
Funding
Abstract
Molecule-based magnets hold promise for a variety of applications in information technologies owing to their chemical tunability. This feature can facilitate the integration of desired magnetic properties alongside additional functionalities within a single material. Although numerous cyanido-bridged assemblies are identified as multifunctional materials at cryogenic temperatures, achieving analogous behavior at room temperature remains a challenge. This study reports a cyanido-bridged compound, which shows ferrimagnetic ordering with a critical temperature exceeding 400 K. This breakthrough is achieved through the mechanochemical synthesis of vanadium(II)-hexacyanomolybdate(III) Prussian Blue Analog (PBA) under anhydrous conditions. The ferrimagnetic order is evidenced by SQUID (SQUID = superconducting quantum interference device) magnetometry and X-ray Magnetic Circular Dichroism (XMCD) spectroscopy. Both techniques unambiguously confirm the antiparallel alignment of vanadium and molybdenum magnetic moments. As a result, hexacyanomolybdate(III) is experimentally established as a viable precursor for the preparation of a new generation of high-temperature molecule-based magnets and multifunctional materials.
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