ArticleChemical science2026
Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Trigonal Phosphine Umpolung: Electrophilicity Driven by a Redox-Active Boron Cluster.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
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8 authors.
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Abstract
Pincer-ligated phosphoranides constitute a relatively underexplored subclass of main-group compounds whose distinctive structural and electronic properties are now attracting renewed interest. In this study, we report the synthesis, full characterization, and novel photoreactivity of O,N,O-pincer ligated phosphoranide anions. Upon visible-light irradiation, these species engage in single-electron transfer (SET) processes with various aryl halides, enabling the formation of C-P and C-C bonds. A combination of electrochemical studies and TD-DFT calculations supports a mechanism involving the formation of electron donor-acceptor (EDA) complexes, followed by light-induced SET and radical recombination. These findings introduce these phosphoranides as a versatile platform for photochemical transformations and underscore the broader potential of main-group frameworks in light-driven redox chemistry.
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