ReviewBeilstein journal of organic chemistry2025
Transformation of the cyclohexane ring to the cyclopentane fragment of biologically active compounds.
Review in Beilstein journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The review is devoted to strategies for contraction of six-membered cycles in the synthesis of functionalized cyclopentane/enones, which are biologically active compounds. The main synthetic methods of ring contraction (ozonolysis-aldol condensation, ozonolysis-Dieckmann reaction, Baeyer-Villiger cleavage-Dieckmann reaction) and rearrangements (benzil, semipinacol, with the participation of thallium- and iodine-based oxidants, photochemical, Wolff, Meinwald, Wagner-Meerwein and Favorskii) are presented. The review summarizes literature data covering the last 12 years, with some exceptions of earlier works due to the importance of the published information.
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