ArticleAngewandte Chemie (International ed. in English)2026
Electrooxidative Divergent Halocyclizations of Ambident Amides.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Overriding the radical polarity matching principle: selective chlorohydroxylation of electron-deficient alkenes enabled by Ce photocatalysis.Chemical science · 2026Article
- Electrooxidative Divergent Halocyclizations of Ambident Amides.Angewandte Chemie (International ed. in English) · 2026Article
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5 authors.
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Abstract
Herein, we report a divergent electrochemical halocyclization of ambident amides that enables selective formation of either C-O or C-N bonds. Unique chemoselectivity is governed by anodic oxidation conditions, in which haliranium-mediated C-O bond formation proceeds via chloride oxidation, while amidyl radicals guide C-N bond formation under basic conditions. Various approaches to understanding reaction mechanisms have been performed, including cyclic voltammetric analyses, experimental kinetic studies, and in silico experimentation. The developed electrooxidative synthetic method offers broad functional group tolerance, highlighting electrochemistry as a powerful tool for selective halocyclization.
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