Evidence map›Paper›PMID 41216883›Full record

ArticleChemSusChem2026

Metalloporphyrin-Based Cathode for Rechargeable Magnesium-Ion Batteries: Copper Leaching and Interphase Formation.

Tom Philipp, Riccarda Müller, Till Ortmann, Christine Kern, Marcus Rohnke, Simon Schauer, Mika Lindén, Ebrahim Abouzari-Lotf, Thomas Smok, Maximilian Fichtner and 4 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemSusChem, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Tom PhilippInstitute of Analytical and Bioanalytical Chemistry (IABC), Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID https://orcid.org/0000-0003-0139-5131
Riccarda MüllerInstitute of Analytical and Bioanalytical Chemistry (IABC), Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Till OrtmannInstitute of Physical Chemistry and Center for Materials Research, Justus Liebig University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany.
Christine KernInstitute of Physical Chemistry and Center for Materials Research, Justus Liebig University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany.
Marcus RohnkeInstitute of Physical Chemistry and Center for Materials Research, Justus Liebig University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany.ORCID https://orcid.org/0000-0002-8867-950X
Simon SchauerInstitute of Inorganic Chemistry II, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Mika LindénInstitute of Inorganic Chemistry II, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Ebrahim Abouzari-LotfSolid State Chemistry, Helmholtz Institute Ulm (HIU), Helmholtzstraße 11, 89081, Ulm, Germany.ORCID https://orcid.org/0000-0002-0549-4199
Thomas SmokSolid State Chemistry, Helmholtz Institute Ulm (HIU), Helmholtzstraße 11, 89081, Ulm, Germany.
Maximilian FichtnerSolid State Chemistry, Helmholtz Institute Ulm (HIU), Helmholtzstraße 11, 89081, Ulm, Germany.ORCID https://orcid.org/0000-0002-7127-1823
Shirin ShakouriInstitute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
Mario RubenInstitute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.ORCID https://orcid.org/0000-0002-7718-7016
Kerstin LeopoldInstitute of Analytical and Bioanalytical Chemistry (IABC), Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID https://orcid.org/0000-0003-0586-7239
Christine KranzInstitute of Analytical and Bioanalytical Chemistry (IABC), Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID https://orcid.org/0000-0002-6001-0580

Funding

Deutsche Forschungsgemeinschaft 390874152
6 · The paper itself

Abstract

[5,15-bis(ethynyl)-10,20-diphenylporphinato]copper(II) (CuDEPP) composite cathodes for rechargeable magnesium-ion batteries have been investigated before, after, and during initial cycling (pristine, first charging, and consecutive discharging). The initial self-conditioning is studied by scanning electron microscopy and spectroscopy-based methods (energy-dispersive X-ray spectroscopy, total reflection X-ray fluorescence spectrometry, and Raman spectroscopy) as well as time-of-flight secondary ion mass spectrometry (ToF-SIMS) and orbitrap SIMS (Orbi-SIMS). This study shows that copper is released from the active material into the electrolyte solution during the initial cycling at potentials higher than 3.1 V versus Mg

Indexed as

copper leachingCu‐porphyrinosmium tetroxide stainingrechargeable magnesium‐ion batteriestransmetalation

Identifiers

PMID41216883
PMCPMC13080235

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.