Ortho-Carborane-Derived Halogen-Bonded Sandwich Complexes.

Christoph J Vonnemann, Elric Engelage, Jas S Ward, Kari Rissanen, Stefan M Huber

Abstract read

In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

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5 · Who and what money

Authors and funding

5 authors.

Christoph J VonnemannFakultät für Biochemie und Chemie, Ruhr-Universität Bochum, Universitätsstraße 150, 44801, Bochum, Germany.ORCID https://orcid.org/0009-0001-2741-6423

Elric EngelageFakultät für Biochemie und Chemie, Ruhr-Universität Bochum, Universitätsstraße 150, 44801, Bochum, Germany.ORCID https://orcid.org/0000-0003-4640-6260

Jas S WardDepartment of Chemistry, University of Jyväskylä, P.O. Box. 35, Survontie 9 B, Jyväskylä, 40014, Finland.ORCID https://orcid.org/0000-0001-9089-9643

Kari RissanenDepartment of Chemistry, University of Jyväskylä, P.O. Box. 35, Survontie 9 B, Jyväskylä, 40014, Finland.ORCID https://orcid.org/0000-0002-7282-8419

Stefan M HuberFakultät für Biochemie und Chemie, Ruhr-Universität Bochum, Universitätsstraße 150, 44801, Bochum, Germany.ORCID https://orcid.org/0000-0002-4125-159X

Funding

Deutsche Forschungsgemeinschaft EXC 2033 - 390677874 - RESOLV

6 · The paper itself

Abstract

We recently introduced multidentate halogen-bonding receptors based on C-iodinated ortho-Carborane moieties. Following up on our results in solution, which indicated a second binding event for sub-stochiometric concentrations of halide guests, we herein present a systematic co-crystallization study with halides to further evaluate the halogen-bonding capacities of these halogen-bonding catalysts. The obtained solid-state structures include two rare examples of octahedral coordination via halogen bonding of a halide ion by a pair of tridentate receptors.

Indexed as

anion bindinganion recognitioncrystallographyhalogen bondingortho‐carboranes

Identifiers

PMID41208727

DOI10.1002/chem.202502693

PMCPMC12734684

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.