ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Tuning Amorphous-Crystalline Catalytic Interfaces by Mechanochemistry: Cu-Based Metallic Glasses Coupled with Ceria for CO Oxidation.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Amorphous metallic alloys, with their liquid-like atomic-scale structure, are promising candidates for developing unprecedented heterogeneous catalysts due to their non-equilibrium, highly disordered state. This study explores the combination of copper-based metallic glasses with crystalline ceria as catalysts for CO oxidation and preferential CO oxidation. The amorphous/crystalline interfaces are synthesized mechanochemically, offering a cost-effective alternative to the use of precious metals while maintaining high catalytic activity. Key parameters of the ball milling process are optimized, namely milling time and frequency, to enhance the interaction between the disordered metal and crystalline ceria, and the new catalysts are thoroughly characterized using ex situ techniques (XRD, DSC, HAADF-STEM-EDX, H
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