Evidence map›Paper›PMID 41201378›Full record

ArticleJournal of the American Chemical Society2025

Polycyclic Scaffolds through the Intermediacy of Boron-Stabilized Nonclassical Carbocations.

Ling Cheng, Mingkai Zhang, James P Morken

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Ling ChengDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0009-0005-2496-7050
Mingkai ZhangDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0001-5343-1742
James P MorkenDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0002-9123-9791

Funding

New Strategies in Catalytic Organic Synthesis with Organoboron ReagentsR35GM127140 · NIGMS · BOSTON COLLEGE · PI JAMES Patrick MORKEN · 2018 to 2026
$5.1M
Development of Catalytic Conjunctive Coupling ReactionsR01GM118641 · NIGMS · BOSTON COLLEGE · PI MORKEN, JAMES PATRICK · 2017 to 2018
$635k
Bruker D8 VENTURE DiffractometerS10OD030360 · OD · BOSTON COLLEGE · PI LI, BO · 2022 to 2022
$428k
NIGMS NIH HHS R01 GM118641NIGMS NIH HHS R35 GM127140NIH HHS S10 OD030360
6 · The paper itself

Abstract

In the presence of catalytic amounts of Brønsted acid, boron-containing norbornene derivatives undergo a regioselective rearrangement to furnish boron-containing nortricyclanes. The unique stabilization of the putative 2-norbornyl cation by the boron substituent was investigated through both experimental and computational studies. Selective functionalization of the boronic ester product enables access to a diverse array of multisubstituted tricyclic structures, providing opportunities for broader applications.

Identifiers

PMID41201378
PMCPMC12980357

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.