ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Scalable Hollow Fiber Adsorbents for Metal Ion Recovery via Selective In-Pore MOF-808 Growth under Aqueous Conditions.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Scalable Hollow Fiber Adsorbents for Metal Ion Recovery via Selective In-Pore MOF-808 Growth under Aqueous Conditions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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Authors and funding
6 authors.
Funding
Abstract
Selective in situ growth of metal-organic frameworks (MOFs) within polymeric supports under mild, aqueous conditions remains a synthetic challenge due to interfacial instability, uncontrolled crystallization, and MOF leaching. Here, this study reports a binding-assisted strategy for the selective in-pore growth of MOF-808 within polyacrylonitrile (PAN)/polyvinyl pyrrolidone (PVP) hollow fibers at 30 °C. Alkaline hydrolysis of PAN introduces anchoring sites for zirconium clusters, while ethanol-assisted solvation promotes MOF crystallization under ambient conditions. The spatial distribution and surface charge of hydrolyzed PVP suppress MOF nucleation on the outer surface, enabling uniform in-pore growth with 34 wt.% loading and > 99% retention after ultrasonication. Post-synthetic functionalization with ethylenediaminetetraacetic acid (EDTA) imparts a strong affinity for Pb
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