ArticlePolymer journal2025
Microrheological study on the entanglement dynamics of salt-free polyelectrolyte solutions in the semidilute entangled regime.
Article in Polymer journal, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Sustainable Structural Hot-Melt Adhesives Enabled by Functionalized Crystalline Lamellae.Advanced materials (Deerfield Beach, Fla.) · 2026Article
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7 authors.
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Abstract
We investigate the entanglement dynamics of salt-free aqueous solutions of poly(sodium styrenesulfonate) (NaPSS) across a range of molecular weights, focusing on the semidilute entangled regime. By combining conventional bulk shear rheometry with diffusing wave spectroscopy (DWS) microrheometry, we characterize key parameters, including the entanglement concentration, plateau modulus, reptation time, and Rouse time of entanglement strands. A clear crossover from polyelectrolyte-like to neutral polymer-like behavior is identified as the degree of polymerization decreases, corresponding to a critical monomer concentration
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