Evidence map›Paper›PMID 41199695›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Through Stronger Hindrance to Higher Reactivity: Influence of the Alkyl Chains on the Activation Energy of Ether Cleavage on Silicon.

Timo Glaser, Gustav F Nolte, Tamam Bohamud, Philip Keller, Mathieu G Silly, Hendrik Weiske, Ralf Tonner-Zech, Michael Dürr

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Timo GlaserInstitut für Angewandte Physik and Zentrum für Materialforschung, Justus-Liebig-Universität Giessen, Heinrich-Buff-Ring 16, 35392, Giessen, Germany.
Gustav F NolteInstitut für Angewandte Physik and Zentrum für Materialforschung, Justus-Liebig-Universität Giessen, Heinrich-Buff-Ring 16, 35392, Giessen, Germany.
Tamam BohamudInstitut für Angewandte Physik and Zentrum für Materialforschung, Justus-Liebig-Universität Giessen, Heinrich-Buff-Ring 16, 35392, Giessen, Germany.
Philip KellerInstitut für Angewandte Physik and Zentrum für Materialforschung, Justus-Liebig-Universität Giessen, Heinrich-Buff-Ring 16, 35392, Giessen, Germany.
Mathieu G SillySynchrotron SOLEIL, L'Orme des Merisiers, Saint Aubin, Gif sur Yvette, 91192, France.
Hendrik WeiskeWilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, 04103, Leipzig, Germany.
Ralf Tonner-ZechWilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, 04103, Leipzig, Germany.
Michael DürrInstitut für Angewandte Physik and Zentrum für Materialforschung, Justus-Liebig-Universität Giessen, Heinrich-Buff-Ring 16, 35392, Giessen, Germany.ORCID https://orcid.org/0000-0002-4676-8715

Funding

Deutsche Forschungsgemeinschaft SFB 1083 - Project ID 223848855State of Hesse LOEWE focus group PriOSS
6 · The paper itself

Abstract

Reactivity in surface chemistry is often discussed in terms of the interaction between surface states and the functional groups of the reacting molecule. Herein, we demonstrate that for finite submonolayer coverage, i.e., surface coverage at which the molecular adsorbates cannot be treated as isolated molecules anymore, the seemingly innocent side chains of the adsorbate can also play a decisive role. For the example of ether cleavage on Si(001), which represents the surface analogue of an

Indexed as

Ab initio calculationsNucleophilic substitutionReaction mechanismsSiliconSurface chemistry

Identifiers

PMID41199695
PMCPMC12759237

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.