Evidence map›Paper›PMID 41198630›Full record

ArticleNature communications2025

Iron/phosphine-catalyzed reductive cross-coupling to construct quaternary carbon centers.

Qiao Zhang, Xiang-Yu Liu, Yu-Yu Li, Ming-Yao Huang, Shou-Fei Zhu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Qiao ZhangAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China.
Xiang-Yu LiuAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China.
Yu-Yu LiAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China.
Ming-Yao HuangAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China.
Shou-Fei ZhuAcademy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China. sfzhu@nankai.edu.cn.ORCID http://orcid.org/0000-0002-6055-3139

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Transition metal-catalyzed C-C reductive coupling reactions avoid the direct use of sensitive metal reagents, representing a practical approach for constructing the skeletons of organic compounds. However, such reactions face significant challenges in constructing quaternary carbon centers. Herein, we report an example of iron-catalyzed reductive cross-coupling reaction of tertiary alkyl halides with allyl halides by using phosphine ligands. A directing strategy is developed for diverse reductive couplings of 3

Identifiers

PMID41198630
PMCPMC12592464

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.