ArticleBeilstein journal of organic chemistry2025
Halogenated butyrolactones from the biomass-derived synthon levoglucosenone.
Article in Beilstein journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Halogenated butyrolactones are found in a variety of bioactive materials and used for the construction of nucleoside analogues. Short procedures for their synthesis have been developed starting with levoglucosenone, which can be obtained in a single step from the pyrolysis of acid-treated cellulose. The processes use inexpensive reagents for the stereoselective C3 functionalization of the bicyclic ring system, with a subsequent Baeyer-Villiger oxidation affording the fluorinated, chlorinated, and brominated dideoxyribonolactones.
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