Evidence map›Paper›PMID 41183800›Full record

ArticleChemphyschem : a European journal of chemical physics and physical chemistry2025

Metal-Induced Tuning of Fullerene Reactivity: Application to Nucleophile Addition.

Corentin Rossi, Anne P Rasmussen, Bérenger Gans, Ugo Jacovella

Abstract read
In one paragraph

Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Metal-Induced Tuning of Fullerene Reactivity: Application to Nucleophile Addition.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Corentin RossiInstitut des Sciences Moléculaires d'Orsay, Université Paris-Saclay, CNRS, 91405, Orsay, France.ORCID https://orcid.org/0000-0002-5903-9933
Anne P RasmussenInstitut des Sciences Moléculaires d'Orsay, Université Paris-Saclay, CNRS, 91405, Orsay, France.ORCID https://orcid.org/0000-0003-1093-6163
Bérenger GansInstitut des Sciences Moléculaires d'Orsay, Université Paris-Saclay, CNRS, 91405, Orsay, France.ORCID https://orcid.org/0000-0001-9658-2436
Ugo JacovellaInstitut des Sciences Moléculaires d'Orsay, Université Paris-Saclay, CNRS, 91405, Orsay, France.ORCID https://orcid.org/0000-0003-2152-261X

Funding

Agence Nationale de la Recherche ANR-22-CE29-0013Villum Fonden VIL71404
6 · The paper itself

Abstract

Endohedral metallofullerenes (EMFs) are a unique class of hybrid molecules formed by encapsulating metal atoms within carbon cages (fullerenes), giving rise to distinctive properties that differ from empty fullerenes. Extensive research has focused on optimizing the synthesis, extraction, isolation, and characterization of EMFs, along with investigating their physicochemical properties and potential applications in areas such as electronics, photovoltaics, biomedicine, and materials science. Here, the use of a laser vaporization source combined with ion mobility and mass spectrometry is demonstrated to characterize and isolate EMF structures, enabling further investigation of their gas-phase chemical properties. This approach is illustrated through a comparative study of the reactivity of empty carbon cages and calcium EMFs in the nucleophilic addition of pyridine.

Indexed as

fullerenesgas‐phase reactionsisomerskineticsmass spectrometry

Identifiers

PMID41183800
PMCPMC12677715

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.