Evidence map›Paper›PMID 41178284›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides.

Peter J Shaw, Gary S Nichol, Jennifer A Garden

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Peter J ShawSchool of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ, UK.ORCID https://orcid.org/0009-0007-7153-8640
Gary S NicholSchool of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ, UK.ORCID https://orcid.org/0000-0002-1597-3679
Jennifer A GardenSchool of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ, UK.ORCID https://orcid.org/0000-0002-9027-4931

Funding

Medical Research Council MR∖T042710∖1The University of Edinburgh
6 · The paper itself

Abstract

Chemical C-H functionalisation is traditionally the domain of potent organolithium bases that require cryogenic conditions, whereas biologically inspired C-H functionalisation can be executed by transition metal-oxo species. Blending these chemical and biological approaches, this work exploits magnesium-oxo complexes for selective C-H deprotonation at ambient temperature. Overall, three low valent magnesium(I) dimers, [

Indexed as

Cleavage reactionsMagnesiumSubvalent compounds

Identifiers

PMID41178284
PMCPMC12723457

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.