Evidence map›Paper›PMID 41178041›Full record

ArticleJournal of the American Chemical Society2025

Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.

Arun Sridharan, Daniel L M Suess

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Arun SridharanDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.ORCID 0000-0001-9249-8894
Daniel L M SuessDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.ORCID 0000-0002-0916-1973

Funding

Modeling the Organometallic Chemistry of Radical S-adenosylmethionine EnzymesR01GM136882 · NIGMS · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI SUESS, DANIEL LEIF MIGDOW · 2020 to 2024
$1.5M
Chemical Approaches to Understanding the Mechanisms of Iron-Sulfur EnzymesR35GM156872 · NIGMS · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI Daniel Leif Migdow Suess · 2025 to 2026
$1.2M
NIGMS NIH HHS R01 GM136882NIGMS NIH HHS R35 GM156872
6 · The paper itself

Abstract

Imido complexes of high-spin 3d metals can feature N subvalency, wherein configurations with hole character at N contribute significantly to the ground state electronic structure. Reported herein are the synthesis and characterization of a series of Fe-S cluster terminal imido complexes isolated in four charge states, [(IMes)

Identifiers

PMID41178041
PMCPMC12803629

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.