Evidence map›Paper›PMID 41171467›Full record

ArticleMikrochimica acta2025

Ultrasensitive electrochemical detection of glyphosate using a Pd-decorated Cit-HAP hybrid electrode.

Dorsaf Bouazzi, Jassem Wannassi, Maria Teresa Caccamo, Salvatore Magazù, Nicole Jaffrezic-Renault, Houcine Barhoumi, Bechir Badraoui

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Article in Mikrochimica acta, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Dorsaf BouazziDipartimento di Ingegneria, Università di Messina, C.da Di Dio, Messina, 98166, Italy.
Jassem WannassiLaboratory of Interfacial and Advanced Materials, Monastir Faculty of Sciences, University of Monastir, Monastir, 5019, Tunisia.
Maria Teresa CaccamoDipartimento di Scienze Matematiche Informatiche Scienze Fisiche e Scienze della Terra, Università di Messina, Viale F. Stagno d'Alcontres 31, Messina, 98166, Italy. mcaccamo@unime.it.
Salvatore MagazùDipartimento di Scienze Matematiche Informatiche Scienze Fisiche e Scienze della Terra, Università di Messina, Viale F. Stagno d'Alcontres 31, Messina, 98166, Italy.
Nicole Jaffrezic-RenaultUTINAM Institute, Marie and Louis Pasteur University, Besançon, 25000, France.
Houcine BarhoumiLaboratory of Interfacial and Advanced Materials, Monastir Faculty of Sciences, University of Monastir, Monastir, 5019, Tunisia.
Bechir BadraouiLaboratory of Condensed Matter and Nanosciences, Faculty of Sciences of Monastir, University of Monastir, Monastir, 5019, Tunisia.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The fabrication of a novel electrochemical sensor for the sensitive and selective detection of glyphosate is reported. It is based on a palladium-doped, citrate-functionalized hydroxyapatite composite (0.5 wt% Pd–wCitHAP), where w represents the molar ratio ncitric/nCa²⁺ (0, 0.2, 0.4, 0.6). The multifunctional composite presents a high surface area associated with the biocompatibility of hydroxyapatite, the chelating properties of citrate, and the electrocatalytic activity of palladium nanoparticles, resulting in a synergistic sensing platform. The modified glassy carbon electrode (0.48Pd-0.6CitHAP/GCE) exhibited a wide linear response range from 0.045 µM to 10 µM with a detection limit of 0.045 µM (S/N = 3). The sensor also demonstrated high selectivity against common interfering species, excellent reproducibility (RSD = 2.56%), and long-term stability over 15 days. Practical applicability was validated by successful detection of glyphosate in tap water, rainwater, and agricultural runoff, with recoveries ranging from 95% to 104%. This cost-effective and portable sensor offers a promising alternative to conventional methods for real-time monitoring of glyphosate in environmental matrices.

Indexed as

Citrate-functionalized hydroxyapatiteDifferential pulse voltammetryElectrochemical sensorGlyphosate detectionModified glassy carbon electrodePalladium nanoparticles

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.