ArticleSmall (Weinheim an der Bergstrasse, Germany)2025
Observing Transient Breathing States of MIL-53 Homologues Using In Situ Single Crystal 3D Electron Diffraction.
Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Developing efficient mechanochemical routes to porous metal-organic polyhedra, supported by 3D electron diffraction.Chemical science · 2026Article
- Unlocking the door for synergizing expansion-capacity in Si anodes: breathable flexible MOFs.Chemical science · 2026Review
- 3D electron diffraction shows structural flexibility in rare Zn(II) paddlewheel-based metal-organic polyhedra.Chemical communications (Cambridge, England) · 2026Article
- Cluster Anion Substitution Tunes Flexibility and Porosity of MIL-53(Sc)-fum Conformational Isomers Isolated by Solvent-Induced MOF-to-MOF Self-Assembly.Journal of the American Chemical Society · 2026Article
- Solid-state molecular organometallic chemistry (SMOM): a user guide toDalton transactions (Cambridge, England : 2003) · 2026Review
- Observing Transient Breathing States of MIL-53 Homologues Using In Situ Single Crystal 3D Electron Diffraction.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
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Authors and funding
8 authors.
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Abstract
The MIL-53 series of metal-organic frameworks (MOFs) is considered archetypal for flexible MOFs, with desolvated materials rapidly transitioning between open and closed phases in a stepwise breathing process in response to changes in temperature under ambient pressure conditions. Herein, the differing structures of MIL-53(Cr) and MIL-53(Ga) during breathing - hydrated and anhydrous, closed and open pore-are characterized by in situ single crystal 3D electron diffractionthrough varying sample conditions within the electron diffractometer. In doing so, the crystal structures of nine intermediate phases are uncovered that together represent the continuous breathing of MIL-53 under vacuum, in stark contrast to ambient pressure stepwise breathing. In addition, these structures offer insight into particle-to-particle structural heterogeneity that are averaged out by conventional powder X-ray diffraction measurements, and may begin to explain metal-dependent adsorption phenomena observed across the MIL-53 homologues. In situ 3D electron diffraction is therefore expected to become a powerful tool for in-depth structural investigations of flexible porous materials.
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