Evidence map›Paper›PMID 41157007›Full record

ReviewMaterials (Basel, Switzerland)2025

A Review of the Intrinsic Chemical Stability Challenge in Operational Perovskite Photovoltaics.

Huān Bì, Zhen Wang, Zhenhua Xu

Abstract readReview
In one paragraph

Review in Materials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Perovskite Heterostructures for Optoelectronic Applications.Advanced materials (Deerfield Beach, Fla.) · 2026
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Huān BìInfo-Powered Energy System Research Center (i-PERC), The University of Electro-Communications, Tokyo 182-8585, Japan.ORCID 0000-0001-7680-9816
Zhen WangKey Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China.
Zhenhua XuSchool of Materials Science and Engineering, NingboTech University, Ningbo 315100, China.ORCID 0000-0003-0919-545X

Funding

Natural Science Foundation of Jiangsu Province, China Grant BK20210545Ningbo Science and Technology Project 2022-DST-004
6 · The paper itself

Abstract

Although the power conversion efficiency of perovskite photovoltaics (PVs) has achieved significant progress, the operational stability is still a critical issue for their commercialization. Compared to inorganic semiconductor materials, organic species in perovskites are intrinsically unstable under long-term illumination, heat, and bias stresses. These organic species exhibit higher chemical reactivity, which can complicate the degradation mechanisms or model of perovskite PVs. In this review, we analyzed the types of chemical reactions for different organic species. The chemical instability mainly stems from the deprotonation of A-site ammonium cations, X-site halide ion migration, and oxidation of halide ions, which can even mutually influence one another. We systematically discuss the effect of this chemical instability on perovskite structure degradation under device operation. These special chemical evolutions will accelerate perovskite PVs' degradation. Then, strategies to mitigate these reactions for enhanced operational stability are introduced. Despite substantial progress in the operational stability of perovskite PVs, achieving an operational lifetime comparable to crystalline silicon remains challenging. Therefore, a deep understanding of intrinsic perovskite structure degradation should become a research focus, contributing to improvement in the operational lifetime of perovskite PVs.

Indexed as

deprotonation of methylammonium cationshalide ions migrationintrinsic chemical stabilityperovskite photovoltaicredox of halide ions

Identifiers

PMID41157007
PMCPMC12565889

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.