The Influence of Pulsed Superimposed DC Electric Field Synergistically Inducing Orientation Arrangement of BNNSs on Thermal Properties of Epoxy Composites.

Modern power systems require better heat dissipation and thermal stability, but traditional low-filler composites cannot significantly enhance thermal conductivity. To address this issue, electric field induction technology orientation can efficiently orient boron nitride nanosheets (BNNSs), thereby improving the thermal conductivity of epoxy composites composed of BNNSs as the thermally conductive filler. In this study, an innovative approach employing a pulsed superimposed direct current (DC) electric field to synergistically induce filler orientation is used to construct efficient thermally conductive channels. The study found that the thermal conductivity of the composite prepared by superimposing an 8 kV/mm pulsed electric field on a 30 V/mm DC electric field is about 0.474 W/(m·K), which is 34.66% higher than that prepared by only a pulsed-induced field and 17.5% higher than the theoretical superposition value. Similarly, the composite prepared by superimposing a 4 kV/mm pulsed electric field on a 70 V/mm DC electric field increased to about 0.464 W/(m·K), which is 27.47% higher than that prepared by only a DC-induced field and 12.4% higher than the theoretical superposition value. These results indicate that the superimposed electric field treatment synergistically improves the thermal conductivity of the composite. Compared to other materials, composites prepared using the superimposed pulsed and DC electric field induction also exhibit superior thermal stability. This strategy effectively addresses the issue of material thermal aging caused by insufficient thermal conductivity, providing innovative ideas and a solid theoretical foundation for material design and thermal management.