ArticleChemphyschem : a European journal of chemical physics and physical chemistry2025
Site Preferences of Copper and Cobalt Monobenzo Porphyrins in a Trans-Dibenzo Adsorption Structure on Cu(111).
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Site Preferences of Copper and Cobalt Monobenzo Porphyrins in a Trans-Dibenzo Adsorption Structure on Cu(111).Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
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Authors and funding
11 authors.
Funding
Abstract
Using scanning tunneling microscopy, Cu and Co tetraphenyl monobenzo porphyrins are used as probe molecules to better understand the T-type interactions within well-ordered islands of Cu and Co tetraphenyl trans-dibenzo porphyrins on Cu(111). The islands are made up of molecular rows, held together by T-type interactions between isoindole and phenyl rings of adjacent molecules. The monobenzo molecules are found to be depleted within the bulk of the molecular rows and enriched at the edges terminating the rows. By counting over 50 000 molecules and using equilibrium considerations, the T-type interaction energies within the trans-dibenzo islands are estimated and the derived values are compared to values previously calculated with density functional theory, which find very good agreement for Cu-TPtdBP but less satisfying agreement for Co-TPtdBP.
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