ArticleChemical science2026
The organophosphorus synthesis triangle: introducing methods for the missing quaternization and de-quaternization routes.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In organophosphorus chemistry, several established reactions, such as the conversion of phosphorus trichloride into tertiary phosphines, followed by oxidation and quaternization to form phosphine oxides and phosphonium salts, are widely recognized and routinely applied. In contrast, other potentially valuable transformations, including reverse or complementary versions of these standard synthetic routes, remain largely unexplored or technically challenging. This work introduces two new reaction pathways that broaden the scope of organophosphorus synthesis. The first involves a P-C bond-forming process that enables interconversion of symmetrical phosphine oxides, such as triphenylphosphine oxide (Ph
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