ArticleNational science review2025
Accelerating lithium-ion pre-desolvation and transport via glassy MOF for fast-charging and high-energy-density lithium-ion batteries.
Article in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Nanoporous Metal-Organic Framework Interphase Stabilized NiChemSusChem · 2026Article
- Metal-organic framework glass enables durable sodium-ion storage for hard carbon negative electrodes.Nature communications · 2026Article
- Porous Organic Frameworks for Lithium-Metal Anodes: Design Strategies, Mechanisms, and Future Perspectives.Nanomaterials (Basel, Switzerland) · 2026Review
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Authors and funding
8 authors.
Funding
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Abstract
Conventional graphite anodes in lithium-ion batteries (LIBs) suffer from limited fast-charging capability and lithium dendrite growth, particularly at high current densities. This work introduces a glassy metal-organic framework (MOF glass) that simultaneously enables easy lithium-ion pre-desolvation and fast Li⁺ transport. The MOF glass-coated graphite (glass@graphite) forms a distinctive double-layer structure during initial discharge: an electron-insulating outer layer with rigid 2.93 Å pores that facilitates easy Li⁺ pre-desolvation, and a Li₃P-rich inner layer that ensures rapid lithium-ion conduction. The outer layer's pre-desolvation effect generates a highly aggregated electrolyte within MOF channels, promoting formation of a stable anion-derived LiF-dominated solid electrolyte interphase. The resulting partially desolvated Li⁺ species readily penetrate the ion-conducting inner layer, enabling ultrafast diffusion. When coupled with LiNi
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