Evidence map›Paper›PMID 41136882›Full record

ArticleJournal of the American Chemical Society2025

Probing Voltage- and Electrolyte-Dependent Monolayer Dynamics with 2D-IR Spectroscopy.

Austin B Gilbert, Wonjae Jeong, Kyle R Billings, Aritri Biswas, Matthew J Ryan, Kijeong Kwac, Minhaeng Cho, Alexei A Kananenka, Martin T Zanni

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Mixed Domain IR-Hyper-Raman Four Wave Mixing Spectroscopy.The journal of physical chemistry letters · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Austin B GilbertDepartment of Chemistry, University of Wisconsin─Madison, Madison, Wisconsin 53706, United States.ORCID 0000-0003-2972-6465
Wonjae JeongDepartment of Chemistry, University of Wisconsin─Madison, Madison, Wisconsin 53706, United States.ORCID 0009-0006-2819-4128
Kyle R BillingsDepartment of Physics and Astronomy, University of Delaware, Newark, Delaware 19716, United States.
Aritri BiswasDepartment of Physics and Astronomy, University of Delaware, Newark, Delaware 19716, United States.ORCID 0000-0003-1021-5550
Matthew J RyanDepartment of Chemistry, University of Wisconsin─Madison, Madison, Wisconsin 53706, United States.ORCID 0000-0003-1633-9087
Kijeong KwacCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Seoul 02841, Republic of Korea.ORCID 0000-0002-8100-3662
Minhaeng ChoCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Seoul 02841, Republic of Korea.ORCID 0000-0003-1618-1056
Alexei A KananenkaDepartment of Physics and Astronomy, University of Delaware, Newark, Delaware 19716, United States.ORCID 0000-0001-9422-7203
Martin T ZanniDepartment of Chemistry, University of Wisconsin─Madison, Madison, Wisconsin 53706, United States.ORCID 0000-0001-7191-9768

Funding

PowerEdge XE8640 GPU cluster for molecular dynamics simulations and machine learning computational vibrational spectroscopy of ion channelsR35GM150963 · NIGMS · UNIVERSITY OF DELAWARE · PI Alexei Kananenka · 2023 to 2026
$1.3M
NIGMS NIH HHS R35 GM150963
6 · The paper itself

Abstract

Little is known about structural dynamics at electrode surfaces under applied potential. Here, we report 2D-IR spectra of a 4-mercaptobenzonitrile monolayer on a gold electrode, revealing chemical exchange between two subensembles on sub- to tens-of-picoseconds time scales. Dynamics are measured in 100 mM MgCl

Identifiers

PMID41136882
PMCPMC12593391

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.