ArticleChemical science2025
Installation of cationic phosphorus on dimethyldihydropyrene photoswitches: expanding the atomic repertoire towards far-red photoswitching in water.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
- Multistate photoswitches beyond on and off.Nature communications · 2026Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We have synthesized for the first time a small library of negative photochromic dimethyldihydropyrene phosphonium salts (DHPPs) that can be activated by red and far-red (up to 740 nm) photons in a quantitative manner in the so-called "biological window". The intriguing feature of this particular class is their remarkably fast response in fully aqueous media with an improved ring-opening quantum yield. Additionally, the reversal can be activated upon visible (blue) light irradiation and also under thermal conditions in a quantitative manner, achieving efficient bidirectional visible light-mediated switching rendering this particular class of photoswitches even more attractive towards their potential application in biological premises. Additionally, all-photonic orthogonal photoswitching of a mixture of conventional unsubstituted DHP and one of our modified DHPP derivatives provides a demonstration of multifunctional molecular logic operations.
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Registered trials
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