Evidence map›Paper›PMID 41122052›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Asymmetric Ligand Field Effects in Electron-Rich Heterometallic Extended Metal Atom Chain Compounds.

Rebecca K Walde, Trey C Pankratz, Amelia M Wheaton, Milton Acosta, John F Berry

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Rebecca K WaldeDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI, 53706, USA.ORCID https://orcid.org/0000-0002-3320-2085
Trey C PankratzDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI, 53706, USA.ORCID https://orcid.org/0000-0002-3032-9347
Amelia M WheatonDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI, 53706, USA.ORCID https://orcid.org/0000-0002-7743-9922
Milton AcostaDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI, 53706, USA.
John F BerryDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI, 53706, USA.ORCID https://orcid.org/0000-0002-6805-0640

Funding

ChimeraX -- Next Generation Visualization and Analysis Software for Multiscale ModelingR01GM129325 · NIGMS · UNIVERSITY OF CALIFORNIA, SAN FRANCISCO · PI FERRIN, THOMAS E · 2018 to 2025
$5.2M
MALDI TOF/TOF Mass SpectrometerS10RR024601 · NCRR · UNIVERSITY OF WISCONSIN-MADISON · PI GELLMAN, SAMUEL H. · 2008 to 2008
$376k
National Science Foundation CHE-2246913NCRR NIH HHS S10 RR024601NIGMS NIH HHS R01 GM129325
6 · The paper itself

Abstract

In heterometallic systems, electron donation from the ligands may influence the metal atoms in either a symmetric or asymmetric way, with the expected case being that the more electronegative metal is favored. Here, we describe a systematic study of heterometallic compounds where this expectation is not observed. In this study, we use a modification of the symmetric 2,2'-dipyridylamine (dpa) ligand with electron donating ethyl groups, the 4,4'-diethyl-2,2'-dipyridylamine ligand (dedpa), to prepare heterometallic extended metal atom chain (HEMAC) complexes with formula Mo

Indexed as

bond theorychain structuresmetal‐metal interactionsmultiple bondstransition metals

Identifiers

PMID41122052
PMCPMC12642394

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.