Stereoselective Synthesis of Alkenyl Fluorides and Alkynes by Defluoro Coupling of Trifluoromethyl Arenes.

José L Rosario-Collazo, Courtney Westlund, Hawa Keita, Simon J Meek

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Stereoselective Synthesis of Alkenyl Fluorides and Alkynes by Defluoro Coupling of Trifluoromethyl Arenes.Angewandte Chemie (International ed. in English) · 2025
Article

4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

José L Rosario-Collazo *Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina, 27599-3290, USA.

Courtney Westlund *Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina, 27599-3290, USA.

Hawa KeitaDepartment of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina, 27599-3290, USA.

Simon J MeekDepartment of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina, 27599-3290, USA.ORCID https://orcid.org/0000-0001-7537-9420

Funding

NIH Administrative Supplement to purchase an Agilent 1260 Infinity II SFC SystemR35GM141558 · NIGMS · UNIV OF NORTH CAROLINA CHAPEL HILL · PI MEEK, SIMON JOHN · 2021 to 2025

$1.9M

Institute of General Medical Sciences R35-GM141558NIGMS NIH HHS R35 GM141558

6 · The paper itself

Abstract

A practical method for the stereoselective synthesis of tri- and tetra-substituted 1,2-fluoro-borylalkenes and alkynes by defluoro / C-C coupling of aryl trifluoromethyl groups is disclosed. Transformations convert simple abundant CF

Indexed as

BoronC–F ActivationDefluorofunctionalizationFluorineOlefination

Identifiers

PMID41116283

DOI10.1002/anie.202515710

PMCPMC12636270

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