ArticleJournal of the American Chemical Society2025
Catalytic Enantioselective Diels-Alder Reaction of Dienes with Acyclic and α,β- and β,β-Disubstituted Enones.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Catalytic Asymmetric Cationic Geranyl Cyclizations.Journal of the American Chemical Society · 2026Article
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Authors and funding
8 authors.
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Abstract
Despite the wealth of methods to enantioselectively catalyze Diels-Alder reactions of α,β-unsaturated carbonyl dienophiles, until today, not a single example with an acyclic enone that is either β,β- or α,β-disubstituted has been reported. Herein, we disclose a general Brønsted acid-catalyzed enantioselective Diels-Alder reaction of various aliphatic acyclic disubstituted enones with hydrocarbon dienes featuring diverse steric and electronic properties. The established method has been employed to synthesize several enantiopure targets, including well-known fragrance components such as arborone and the damascones.
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Registered trials
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