ArticleACS omega2025
Different Protecting Groups to Cap Mercapto Propyl Silatrane Affect Water Solubility and Surface Modification Efficiency.
Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
4 authors.
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Abstract
Surface modification is an important field and widely applied to biosensors, biomaterials, and semiconductors. Mercapto propyl trimethoxyl silane (MPTMS) is a most common material applied to surface modification in biosensor chips. However, MPTMS is moisture sensitive, slow to modify reaction rates with substrate surfaces, and unstable due to thiol groups, which restrict the expansibility of MPTMS. Previously, we synthesized mercapto propyl silatrane (MPS) to improve moisture sensitivity and increase reactivity with substrate surfaces. Despite these improvements, MPS still requires a high-polarity organic solvent environment and the thiol groups remain susceptible to oxidation by oxygen. The utility of mercaptan-functionalized films critically depends on their stability under ambient conditions. As global environmental awareness increases, developing stable and environmentally friendly silane molecules has become increasingly important. In this report, we explored different protective groups (acetyl- (Ac-), di-
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