ArticleScientific reports2025
Layered double hydroxides in nanofiltration as a new approach to nitrate removal.
Article in Scientific reports, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
High nitrate concentrations in water present serious risks to human health. This study evaluates two removal strategies: layered double hydroxide (LDH) nanoparticles (NPs) and LDH-incorporated thin-film composite nanofiltration (TFC-NF) membranes to reduce nitrate concentration. First, Mg-Al, Ni-Fe, and Mn-impregnated Zn-Al LDH NPs were co-precipitated, characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) analysis, field emission scanning electron microscopy (FESEM), and zeta potential measurement, and tested in batch adsorption experiments (20 mg/L nitrate solution, 1 g/L adsorbent dosage). Among the LDH NPs tested, Ni-Fe LDH demonstrated the highest nitrate rejection, achieving 13-14% at this concentration, with no significant change with further calcination. Next, the TFC-NF membranes were fabricated by embedding LDH NPs into the support layer; one variant received additional layer-by-layer (LBL) surface modification. The membranes were also characterized using FESEM and then evaluated using a 50 mg/L nitrate solution at 6 bar pressure and 25 °C. The TFC-NF membrane containing 0.25 wt% Mn-impregnated Zn-Al LDH achieved nitrate rejection of 43% with pure water flux (PWF) of 4.5 L/m
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