ArticleChemical science2025
Tunable mechanics and energetics in structurally diverse TNPG-based metal organic networks.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Potassium-Ion-Directed Three-Dimensional Assembly of a Dense and Thermally Robust Nitrogen-Rich Tetrazine Framework.Chemistry, an Asian journal · 2026Article
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9 authors.
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Abstract
Developing high-energy materials that are powerful yet safe requires a careful balance between thermal stability, mechanical strength, and detonation performance. While metal coordination is a known strategy to improve the thermal stability of energetic compounds like trinitrophloroglucinol (TNPG), mono-metallic networks often suffer from diminished detonation performance and increased sensitivity. This work introduces a new class of hetero-metallic metal-organic networks, MM'-TNPG (M/M' = Li, Na, K), that harmonizes all critical performance parameters, including enhanced thermal stability, reduced sensitivity, and high detonation output. Particularly, we present the first systematic correlation between mechanical properties evaluated
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