Evidence map›Paper›PMID 41098493›Full record

ArticleChemical science2025

Enhancing the statistical probability factor in triplet-triplet annihilation photon upconversion

Lukas Naimovičius, Manvydas Dapkevičius, Edvinas Radiunas, Mila Miroshnichenko, Gediminas Kreiza, Carles Alcaide, Paulius Baronas, Yoichi Sasaki, Nobuhiro Yanai, Nobuo Kimizuka and 5 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Lukas NaimovičiusInstitute of Materials Science of Barcelona (ICMAB-CSIC), Universitat Autònoma de Barcelona Bellaterra Barcelona 08193 Spain kasper.moth-poulsen@upc.edu pbharmoria@icmab.es.ORCID https://orcid.org/0000-0002-3358-4108
Manvydas DapkevičiusInstitute of Photonics and Nanotechnology, Vilnius University Saulėtekio av. 3 LT-10257 Vilnius Lithuania.
Edvinas RadiunasInstitute of Photonics and Nanotechnology, Vilnius University Saulėtekio av. 3 LT-10257 Vilnius Lithuania.ORCID https://orcid.org/0000-0002-3333-2242
Mila MiroshnichenkoInstitute of Materials Science of Barcelona (ICMAB-CSIC), Universitat Autònoma de Barcelona Bellaterra Barcelona 08193 Spain kasper.moth-poulsen@upc.edu pbharmoria@icmab.es.
Gediminas KreizaInstitute of Photonics and Nanotechnology, Vilnius University Saulėtekio av. 3 LT-10257 Vilnius Lithuania.
Carles AlcaideInstitute of Computational Chemistry and Catalysis (IQCC) and Department of Chemistry, Universitat de Girona M. Aurèlia Capmany 69 17003 Girona Spain.ORCID https://orcid.org/0000-0002-0611-870X
Paulius BaronasDepartment of Chemical Engineering, Universitat Politècnica de Catalunya EEBE Eduard Maristany 10-14 08019 Barcelona Spain.ORCID https://orcid.org/0000-0002-4141-1485
Yoichi SasakiDepartment of Applied Chemistry, Graduate School of Engineering Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan.
Nobuhiro YanaiDepartment of Applied Chemistry, Graduate School of Engineering Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan.ORCID https://orcid.org/0000-0003-0297-6544
Nobuo KimizukaDepartment of Applied Chemistry, Graduate School of Engineering Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan.
Andrew B PunDepartment of Chemistry and Biochemistry, University of California San Diego 92093 La Jolla CA USA.ORCID https://orcid.org/0000-0002-3052-912X
Miquel SolàInstitute of Computational Chemistry and Catalysis (IQCC) and Department of Chemistry, Universitat de Girona M. Aurèlia Capmany 69 17003 Girona Spain.ORCID https://orcid.org/0000-0002-1917-7450
Pankaj BharmoriaInstitute of Materials Science of Barcelona (ICMAB-CSIC), Universitat Autònoma de Barcelona Bellaterra Barcelona 08193 Spain kasper.moth-poulsen@upc.edu pbharmoria@icmab.es.
Karolis KazlauskasInstitute of Photonics and Nanotechnology, Vilnius University Saulėtekio av. 3 LT-10257 Vilnius Lithuania.ORCID https://orcid.org/0000-0001-7900-0465
Kasper Moth-PoulsenInstitute of Materials Science of Barcelona (ICMAB-CSIC), Universitat Autònoma de Barcelona Bellaterra Barcelona 08193 Spain kasper.moth-poulsen@upc.edu pbharmoria@icmab.es.ORCID https://orcid.org/0000-0003-4018-4927

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We investigated the influence of triisopropylsilyl (TIPS) functionalization on annihilators in triplet-triplet annihilation photon upconversion, specifically focusing on their spin statistical probability factor. A new green-emitting annihilator 3,9-bis((triisopropylsilyl)ethynyl)perylene (TIPS-PY) displaying a record red-to-green TTA-UC quantum yield of 13.7% (50% theoretical maximum) was synthesized. This remarkable efficiency was achieved due to the following features of the TIPS functionalization of PY: (1) retaining a high fluorescence quantum yield of 95%, (2) reduced triplet energy to 1.29 eV enabling efficient triplet energy transfer (∼100%) from the sensitizer PdTPBP (T

Identifiers

PMID41098493
PMCPMC12519238

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.