Evidence map›Paper›PMID 41096341›Full record

ArticlePolymers2025

Kinetics of Carboxylic Acids Formation During Polypropylene Thermooxidation in Water Saturated with Pressurized Oxygen.

Vadim V Zefirov, Polina S Kazaryan, Andrey I Stakhanov, Svetlana V Stakhanova, Mikhail M Ilyin, Ivan A Godovikov, Elizaveta V Shmakova, Andrey G Terentyev, Alexander V Dudkin, Elena P Kharitonova and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Vadim V ZefirovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.ORCID 0000-0001-5671-0528
Polina S KazaryanA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.ORCID 0000-0002-7881-9572
Andrey I StakhanovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.ORCID 0000-0001-7985-1833
Svetlana V StakhanovaDepartment of Analytical Chemistry, Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047 Moscow, Russia.
Mikhail M IlyinA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.ORCID 0000-0002-0214-8573
Ivan A GodovikovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.
Elizaveta V ShmakovaDepartment of Analytical Chemistry, Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047 Moscow, Russia.
Andrey G TerentyevDepartment of Analytical Chemistry, Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047 Moscow, Russia.
Alexander V DudkinDepartment of Analytical Chemistry, Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047 Moscow, Russia.
Elena P KharitonovaFaculty of Physics, M.V. Lomonosov Moscow State University, Leninskie Gory 1-2, 119991 Moscow, Russia.
Marat O GallyamovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.ORCID 0000-0001-7739-3074
Alexei R KhokhlovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russia.

Funding

Ministry of Science and Higher Education of the Russian Federation 075-15-2024-553
6 · The paper itself

Abstract

In this paper we study in detail the products formed during the process of water-assisted thermal oxidative decomposition (TOD) of polypropylene in the presence of pressurized oxygen. A set of techniques has shown that the main decomposition product in such a process is acetic acid with small amounts of other carboxylic acids (formic, propionic, succinic). The kinetics of carboxylic acid formation is studied by means of gas chromatography-mass-spectrometry as well as capillary electrophoresis, and the possible mechanisms behind the products formation are discussed. The role of water is considered based on the results obtained from substituting H

Indexed as

carboxylic acidschemical processingplastic wastepolypropylenethermal oxidative decompositionwet oxidation

Identifiers

PMID41096341
PMCPMC12526518

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.