ArticlePolymers2025
Plasticizer-Enabled Solvent-Free Curing of Self-Healing Binder System for Energetic Materials.
Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Solvent processing hampers the reliability and energy density of self-healing binders for energetic materials. We report a solvent-free curing route for a Diels-Alder self-healing furanyl-terminated polybutadiene enabled by a functional external plasticizer, dibutyl phthalate (DBP), which acts not only to lower the viscosity of the binder but to disperse the high-melting bismaleimide, thereby driving crosslinked network formation. The 50 wt% DBP-plasticized film healed a pre-cut crack in 5 min at 120 °C and recovered nearly full mechanical properties after 24 h at 60 °C. Based on this binder system, a self-healing solid propellant with 80 wt% solid content was solvent-free cast into a dense and void-free grain that healed surface cracks within 5 min at 120 °C. This solvent-free approach overcomes the limitations of solvent-based processing and offers a viable fabrication route for self-healing energetic materials.
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