ArticleJournal of the American Chemical Society2026
A Highly Selective Cobalt Catalyst for Primary Amine Synthesis from Carboxylic Acids, Esters, and Vegetable Oils.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The prevalence of carboxylic acids and esters in nature renders them diverse and conveniently accessible building blocks for chemical synthesis. In this Letter, we present a straightforward cobalt-based catalytic system for the selective synthesis of primary amines from carboxylic acid derivatives and ammonia. The current system has been demonstrated to provide an efficient synthesis route for various amine derivatives and exhibits excellent chemoselectivity despite the complex reaction network. The optimal catalyst offers broad functional group tolerance, with both (hetero)aromatic and aliphatic substrates yielding the desired primary amines in good to excellent yields. The sophisticated Co-triphos
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