ArticleJournal of the American Chemical Society2025
1D Silver Organochalcogenide Semiconductors: Color Tunable Luminescence, Polarized Emission, and Long-Range Exciton Diffusion.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal organochalcogenides (MOCs) represent a promising class of organic-inorganic hybrid semiconductors with unique light-matter interactions. Their hybrid nature enables extensive structural and optoelectronic tunability via ligand engineering. In this study, we systematically modulated the electronic properties of ligands using Cl and Me functional groups, achieving precise control over the optoelectronic properties of Ag-based MOCs. Structural analysis revealed that these MOCs adopt a one-dimensional (1D) chain structure with organic ligands surrounding a Ag-chalcogen core. Density functional theory (DFT) calculations demonstrated that MOCs exhibit characteristics of 1D semiconductors with strongly dispersive conduction and valence bands aligned along the crystal rod directions. Experimentally, the MOCs displayed bright luminescence, with peaks centered between 560 and 690 nm. The substitution of Cl with Me groups in the benzene ligands induced a red shift in both absorption and photoluminescence, corroborated by experimental and theoretical analyses. Further optical measurements indicated that the emission from the MOCs is strongly polarized along the chain directions. Notably, Se-based MOCs exhibited enhanced exciton diffusivity along the chain axis with a diffusion length of 130 nm, which is among the highest reported for covalent systems. The observed trend in carrier diffusivity among individual compounds is attributed to differences in the effective masses of the carriers, as determined by DFT calculations. Our findings offer valuable insights into the systematic structural and property tuning of hybrid semiconductors and highlight the unique characteristics of the 1D MOC family.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.