ArticleJournal of the American Chemical Society2025
Reinventing Chemiluminescence through Redox-Driven Self-Assembly.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Two-Dimensional Supramolecular Architecture of a Dinuclear Platinum(II) Complex Exhibiting Dual Emission in Aqueous Solution.Chemistry, an Asian journal · 2026Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chemiluminescence (CL) typically derives from harvesting the energy released during the cleavage of covalent bonds, wherein molecular substrates are irreversibly consumed to generate electronically excited states. In contrast, regenerative CL seeks to bypass substrate decomposition by using reversible redox processes to produce emissive states, an approach that is largely limited to polypyridyl complexes of Ru(II) and Cr(III). Here, we report a fundamentally distinct chemiluminescence mechanism in which the exergonic reduction of Pt(IV) complexes powers the spontaneous formation of emissive Pt(II) aggregates. Notably, light emission arises not from discrete molecular species but from the self-assembled state, whose electronic structure features a lowered excited-state energy (
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Registered trials
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