Valence restrictive metal-support interaction for boosting catalytic activity of Rh/CeO

Ze-Kai Yu, Mingxiang Jiang, Sheng Dai, Wangcheng Zhan, Zhi-Qiang Wang, Xue-Qing Gong

Abstract read

In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it

0cells of the map it votes in

6citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

Light-Driven Charge Redistribution of Pt Cluster/CeOAngewandte Chemie (International ed. in English) · 2026
Article
Ammonia mediated electrostatic adsorption synthesis of paired subnanoclusters with enhanced hydrogen oxidation performance.Nature communications · 2026
Article
Atomic-level engineering of single-atom catalysts for selective C-C coupling in COChemical science · 2026
Review
Structure-adaptive single-atom nickel catalysts for pure hydrogen peroxide electrosynthesis at industrial current density.Nature communications · 2026
Article
Paramagnetic active sites boosted hydrogenation ofRSC advances · 2026
Article
Understanding alkali metal promotion in hydrogenation catalysis through Strong Metal-Base Interaction.Nature communications · 2026
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Ze-Kai Yu *State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Centre for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China.ORCID http://orcid.org/0009-0008-4244-0799

Mingxiang Jiang *State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China.ORCID http://orcid.org/0009-0008-2531-9700

Sheng DaiKey Laboratory for Advanced Materials, Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China.ORCID http://orcid.org/0000-0001-5787-0179

Wangcheng ZhanState Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China. zhanwc@ecust.edu.cn.ORCID http://orcid.org/0000-0002-0712-4917

Zhi-Qiang WangState Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Centre for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, China. zhiqiangwang@ecust.edu.cn.ORCID http://orcid.org/0000-0001-6293-1474

Xue-Qing GongState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, China. xqgong@sjtu.edu.cn.ORCID http://orcid.org/0000-0002-9566-7427

Funding

Ministry of Science and Technology of the People's Republic of China (Chinese Ministry of Science and Technology) 2021YFA1500700Ministry of Science and Technology of the People's Republic of China (Chinese Ministry of Science and Technology) 2023YFA1508500National Natural Science Foundation of China (National Science Foundation of China) 22203030

6 · The paper itself

Abstract

Metal-support interactions (MSI) profoundly modulate the catalytic properties of supported nanometal catalysts. However, a comprehensive understanding of their underlying mechanisms largely remains elusive. In this work, we propose a novel valence restrictive metal-support interaction (VR-MSI) through systematic theoretical and experimental studies of the various Rh-modified CeO

Identifiers

PMID41083436

DOI10.1021/ja0207551

PMCPMC12518803

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LicenceCC BY-NC-ND

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.