ArticleACS polymers Au2025
Boosting Ionic Conductivity by Ordering Nanoparticles within All-Polymer Poly(ethylene oxide) (PEO) Nanocomposites.
Article in ACS polymers Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Polymer Nanoparticles as Functional Fillers for Composite Electrolytes for Batteries.Industrial & engineering chemistry research · 2026Review
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7 authors.
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Abstract
In this work, we demonstrate that the ordering of ion-conducting nanoparticles within the interlamellar regions of semicrystalline poly-(ethylene oxide) (PEO) enhances its ionic conductivity. Specifically, lithium sulfonamide functional polymeric methacrylic nanoparticles (NPs) measuring 26.4 ± 5.6 nm were aligned within a PEO matrix by controlling the crystallization rate of PEO. Polarized light optical microscopy (PLOM) revealed that the temperature range between 52 and 56 °C allows for sufficiently slow crystallization kinetics to achieve NP ordering. This ordering was observed by using transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS). The alignment of the NPs results in an 8-fold increase in the ionic conductivity of the nanocomposite polymer electrolyte at room temperature, exhibiting lithium single-ion conducting behavior and achieving a value of 4.6 × 10
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