ArticleACS omega2025
Microwave-Assisted Acylation of Hydroxybenzil Derivatives: A Synthetic Approach toward Acyloxy Bis-1,2,4-triazinyl-2,6-pyridine Complexants and Application to Minor Actinide Extraction.
Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Complexant-derived extraction of the minor actinides from lanthanides contained within spent nuclear fuel can assist with closing the nuclear fuel cycle and further strengthening nuclear fission's position as a noncarbon energy source. A method to prepare bisacyloxy benzils leveraging microwave-assisted organic synthesis provided access to 11 not previously-reported bis-1,2,4-triazinyl-2,6-pyridine (BTP) complexants. Definition of the limits of acylation of 2,2'-, 3,3'-, and 4,4'-dihydroxybenzils, the condensation of acylated materials toward a new class of BTP complexants, and preliminary performance data for extraction of the minor An extraction
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