ArticleChemphyschem : a European journal of chemical physics and physical chemistry2025
Spontaneous Mirror-Symmetry Breaking Destabilizes Racemates: A Route to Homochirality and Reversed Chemical Selectivity.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed.
- Spontaneous Mirror-Symmetry Breaking Destabilizes Racemates: A Route to Homochirality and Reversed Chemical Selectivity.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
Several models and experiments yielding to spontaneous mirror-symmetry breaking (SMSB) have been revisited. It is concluded that all show first-order autocatalytic dynamics for the emergence of an enantiomeric excesses (ee). However, first-order autocatalysis is by itself unable to lead to SMSB. Therefore, the emergence of scalemic nonequilibrium stationary state (NESS) is due to racemate destabilization through the coupling of autocatalysis with other enantioselective reactions. In contrast with the nonlinear effects and kinetic control in asymmetric synthesis SMSB appears as the signature of a bifurcation scenario leading to scalemic NESSs. Stoichiometric network analysis points to the potential interest of these autocatalytic networks to interpret the changes in the chemical selectivity between nonenantiomeric competitive replicators in far-from-equilibrium conditions.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.