Evidence map›Paper›PMID 41065432›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Substituent Effects on Sulfur Phenolate Exchange Reactions: Reactivity and Bonding Analysis.

Akash Krishna, Pau Besalú-Sala, F Matthias Bickelhaupt, Guanna Li, Han Zuilhof

Erratum issuedAbstract read
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Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

5 authors.

Akash KrishnaCollege of Biological and Chemical Engineering, Jiaxing University, Jiaxing, 314001, China.
Pau Besalú-SalaDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam, 1081 HZ Amsterdam, The Netherlands.ORCID https://orcid.org/0000-0002-0955-9762
F Matthias BickelhauptDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam, 1081 HZ Amsterdam, The Netherlands.
Guanna LiBiobased Chemistry and Technology, Wageningen University, Bornse Weilanden 9, 6708 WG Wageningen, The Netherlands.ORCID https://orcid.org/0000-0003-3031-8119
Han ZuilhofCollege of Biological and Chemical Engineering, Jiaxing University, Jiaxing, 314001, China.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The Sulfur Phenolate Exchange reaction (SuPhenEx) provides a fluorine-free alternative S(VI) exchange chemistry by substituting nitrophenolate as the leaving group instead of fluoride (as in SuFEx reactions), offering a synthetically appealing and environmentally friendly approach in click chemistry. Despite its significance, the reaction mechanism and the underlying electronic interactions in the course of the reaction have yet to be thoroughly explored at the molecular level. Here, we elucidate the electronic interactions of a series of SuPhenEx model reactions between various para-substituted phenolates (p-R-Ph-O

Indexed as

bonding analysisclick reactionsdensity functional theory calculationssufexsuphenex

Identifiers

PMID41065432
PMCPMC12598377

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.