ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Revealing the Character of Coordination Bonding in 2D Metal-Organic Frameworks.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
5 citing papers in PubMed.
- Zero-Valent Nickel Stabilized in Surface-Supported Metal-Organic Chains.Angewandte Chemie (International ed. in English) · 2026Article
- Altermagnetic Metal-Organic Frameworks.Journal of the American Chemical Society · 2026Review
- Programming Insulator-to-Metallic Transport in Insulating Materials via Surface Single-Atom Engineering.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Spectroscopic Fingerprinting of Coordination-driven Spin States in Metal-organic Architectures.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Revealing the Character of Coordination Bonding in 2D Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
In this contribution, the coordination bond is investigated in a 2D metal-organic framework consisting of nickel and 7,7,8,8-tetracyanoquinodimethane (TCNQ) on a Ag(100) substrate. Using angle-resolved photoemission experiments supported by density functional theory calculations, the bonding is characterized as a result of the hybridisation between the ligand orbitals and the metal d-states. Unambiguous experimental fingerprints are presented for such a mechanism by revealing the splitting in energy of the frontier molecular orbitals into sets of bonding/antibonding states in the 2D metal-organic framework. Furthermore, a qualitative analysis of the energy level alignment is given for the transition metal inside the coordination environment and discuss the role of the network structure on the formation of such hybrid states.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.